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    An electrochemically polymerized and assembled cyclopalladated bi-thiophene imine for catalyzing coupling reactions: a modern strategy to enhance catalytic activity

    Year: 2015

    Journal: RSC ADVANCES, Vol. 5, p 16654-16663, 20170208

    Authors: Zou, Keke; Liu, Hui; Li, Tiesheng; Chen, Penglei; Liu, Minghua; Wu, Yangjie

    Organizations: Zhengzhou Univ, Coll Chem & Mol Engn, Key Lab Nanoinformat Mat Zhengzhou, Zhengzhou 450052, Peoples R China; Chinese Acad Sci, Inst Chem, CAS Key Lab Colloid Interface & Chem Thermodynam, Beijing 100190, Peoples R China

    The catalytic activity and recyclability of self-assembled electrochemical polymerized 1,2-bis(3-thiophene imine) ethylene (B3TIE) and N-octadecyl-3-thiophenylimine (NOTPI) monolayers (ECP-SABM) with Li2PdCl4 were enhanced compared to those prepared without an electrochemical polymerized monolayer (SABM). This was also proven to be a universal rule for thiophene derivatives with these methods.