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Dual-Functional Beeswaxes on Enhancing Antimicrobial Activity and Water Vapor Barrier Property of Paper

Year: 2013

Journal: ACS Appl. Mater. Interfaces, 2013, 5 (8), pp 3464–3468, 20131119

Authors: Dan Zhang 1 2 and Huining Xiao *1

Organizations: 1 Department of Chemical Engineering, University of New Brunswick, Fredericton, NB, Canada E3B 5A32 School of Materials Science and Engineering, Shijiazhuang Tiedao University, 17 Northeast, Second Inner Ring, Shijiazhuang, Hebei, People’s Republic of China 050043

The guanidine-based antimicrobial polymers were grafted onto the surface of beeswax latex particles stabilized with or without amphoteric surfactant, n-dodecyl-N,N-dimethylglycine. N-(3-Dimethylaminopropyl)-N′-ethylcarbodiimide hydrochloride (EDC) was used as a coupling reagent to introduce the covalent bonding or ensure sufficient binding force. The resulting novel beeswax latexes were utilized as a dual-functional paper additive, which improved both water-vapor resistance and antimicrobial activities of the paper. Compared with control sample, the water vapor transmission rate of the paper was reduced significantly. The antimicrobial activity of paper against E. coli was also improved substantially even at a low dosage of the beeswax latex derivatives (20 mg/g fiber).