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Effect of Gas Diffusion Layer Composition on the Performance of Direct Methanol Fuel Cells

Year: 2010

Journal: Electrochemical and solid-state letters, Volume 13, Issue 7, pp. B73-B75 (2010), 20111221

Authors: Francisco Alcaide,1 Garbiñe Álvarez,1 Pere L. Cabot,2 Hans-Jürgen Grande,1 and Oscar Miguel1

Organizations: 1 Energy Department, CIDETEC-IK4, San Sebastián 20009, Spain, 2 Laboratori d'Electroquímica de Materials i del Medi Ambient, Departamento de Química Física, Universitat de Barcelona, 08028 Barcelona, Spain

The effect of the cathode gas diffusion layer compositions on theperformance of direct methanol fuel cells has been investigated. Morphological and textural properties of different diffusion layers have been characterized. Experiments in a single cell show that the use of a microporous layer (MPL) made with acetylene black instead of furnace carbon black results in higher cell voltages and powerdensities. This has been explained by a smaller mass-transfer resistance in the cathode diffusion layer due to a more suitablestructure of the MPL when using acetylene black.