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    Enhancement of the electrochemical behaviour and biological performance of Ti-25Ta-5Zr alloy by thermo-mechanical processing

    Year: 2014

    Journal: MATERIALS SCIENCE & ENGINEERING C-MATERIALS FOR BIOLOGICAL APPLICATIONS, Vol. 38, p 127-142, 20150722

    Authors: Cimpean, Anisoara; Vasilescu, Ecaterina; Drob, Paula; Cinca, Ion; Vasilescu, Cora; Anastasescu, Mihai; Mitran, Valentina; Drob, Silviu Iulian

    Organizations: Univ Bucharest, Dept Biochem & Mol Biol, Bucharest 050095, Romania; Acad Romana, Inst Phys Chem Ilie Murgulescu, Dept Electrochem & Corros, Bucharest 060021, Romania; Politehn Univ, Fac Mat Sci & Engn, Bucharest 060042, Romania

    A new Ti-25Ta-5Zr alloy based only on non-toxic and non-allergic elements was elaborated in as-cast and thermo-mechanical processed, recrystallized states (XRD and SEM) in order to be used as candidate material for implant applications. Its long-term interactions with Ringer-Brown and Ringer solutions of different pH values and its cytocompatibility were determined. The thermo-mechanically processed alloy has nobler electrochemical behaviour than as-cast alloy due to finer microstructure obtained after the applied treatment. Corrosion and ion release rates presented the lowest values for the treated alloy. Nyquist and Bode plots displayed higher impedance values and phase angles for the processed alloy, denoting a more protective passive film. SEM micrographs revealed depositions from solutions that contain calcium, phosphorous and oxygen ions (EDX analysis), namely calcium phosphate. An electric equivalent circuit with two time constants was modelled. Cell culture experiments with MC3T3-E1 pre-osteoblasts demonstrated that thermo-mechanically processed Ti-25Ta-5Zr alloy supports a better cell adhesion and spreading, and enhanced cell proliferation. Altogether, these data indicate that thermo-mechanical treatment endows the alloy with improved anticorrosion and biological performances. (C) 2014 Elsevier B.V. All rights reserved.