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    Graphitic carbon nitride modified by thermal, chemical and mechanical processes as metal-free photocatalyst for the selective synthesis of benzaldehyde from benzyl alcohol

    Year: 2017

    Journal: J. Catal., Volume 353, SEP, page 44–53

    Authors: Lima, Maria J.; Silva, Adrian M. T.; Silva, Claudia G.; Faria, Joaquim L.

    Organizations: project "AIProcMat@N2020 - Advanced Industrial Processes and Materials for a Sustainable Northern Region of Portugal 2020" - Norte Portugal Regional Operational Programme (NORTE 2020), under the Portugal 2020 Partnership Agreement, through the(ERDF) [NORTE-01-0145-FEDER-000006]; ERDF through COMPETE2020 - Programa Operational Competitividade e Internacionalizacao (POCI) [POCI-01-0145-FEDER-006984]; FCT - Fundacao para a Ciencia e a Tecnologia; FCT [PD/BD/52623/2014]; FCT Investigator Programme [IF/01501/2013, IF/00514/2014]; European Social Fund; Human Potential Operational Programme

    Keywords: Photocatalysis; Selective oxidation; Benzyl alcohol; Benzaldehyde; Carbon nitride

    The selective photocatalytic conversion of benzyl alcohol to benzaldehyde was studied in aqueous medium, as alternative to common organic solvents, in combination with environmentally friendly conditions: metal-free catalysts based on graphitic carbon nitride (g-C3N4), natural pH, ambient temperature and pressure, and light emitting diodes (LEDs) as high efficient lighting source. g-C3N4 was synthesized by thermal condensation of dicyandiamide and the photocatalytic performance evaluated in terms of different post-treatment routes: thermal, mechanical and chemical. Several temperatures (400, 450 and 500 degrees C), times of mechanical treatment (1.5, 3.0 and 8.0 h) and protic acids (H2SO4, HCl and HNO3) were tested. The post-treatments significantly enhance photocatalytic conversion and yield, with minimal compromise on selectivity. The photocatalyst obtained upon thermal pos-treatment of g-C3N4 at 500 degrees C, which had the better performance (66% conversion, 59% yield, and 90% selectivity at four hours of irradiation), was found to have the highest BET surface area (87 m(2) g(-1)). (C) 2017 Elsevier Inc. All rights reserved.
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