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In situ investigation of dye adsorption on TiO2 films using a quartz crystal microbalance with a dissipation technique

Year: 2012

Journal: Phys. Chem. Chem. Phys., 2012,14, 9037-9040, 20120618

Authors: Hauke A. Harms 1, Nicolas Tétreault 1, Viktoria Gusak 2, Bengt Kasemo 2 and Michael Grätzel 1

Last authors: Michael Grätzel

Organizations: 1. Laboratory of Photonics and Interfaces,École Polytechnique Fédérale de Lausanne, 1015 Lausanne, Switzerland 2. Chemical Physics Group,Department of Applied Physics,Chalmers University of Technology, 412 96 Göteborg, Sweden

Country: Sverige, Sweden, Switzerland

Dye adsorption plays a crucial role in dye-sensitized solar cells. Herein, we demonstrate an in situ liquid-phase analytical technique to quantify in real time adsorption of dye and coadsorbates on flat and mesoporous TiO2 films. For the first time, a molar ratio of co-adsorbed Y123 and chenodeoxycholic acid has been measured.