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Laundering Durability of Photocatalyzed Self-Cleaning Cotton Fabric with TiO2 Nanoparticles Covalently Immobilized

Year: 2013

Journal: ACS Applied Materials & Interfaces, 2013, 5 (9), pp 3697-3703, 20130926

Authors: Ming Yu, Ziqiang Wang, Hanzhou Liu, Siyuan Xie, Jingxia Wu, Haiqing Jiang, Jianyong Zhang, Linfan Li, Jingye Li

Organizations: TMSR Research Center and CAS Key Lab of Nuclear Radiation and Nuclear Energy Technology, Shanghai Institute of Applied Physics, Chinese Academy of Sciences, Shanghai 201800, P. R. China; University of Chinese Academy of Sciences, Beijing 100049, P. R. China

Photocatalyzed self-cleaning cotton fabrics with TiO2 nanoparticles covalently immobilized are obtained by cograft polymerization of 2- hydroxyethyl acrylate (HEA) together with the surface functionalized TiO2 nanoparticles under γ-ray irradiation. The covalent bonds between the TiO2 nanoparticles and cotton fabrics bridged by poly(2-hydroxyethyl acrylate) (PHEA) graft chains is strong enough to survive 30 accelerated laundering circles, equivalent to 150 commercial or domestic launderings.