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Linear-Dendritic Block Copolymers Based on N-Isopropylacrylamide and Perfluorinated Polyphenylenegermane: Synthesis and Properties at Various Interfacial Boundaries

Year: 2017

Journal: Polym. Sci. Ser. B, Volume 59, NOV, page 708–717

Authors: Zamyshlyayeva, O. G.; Smirnov, E. A.; Zakharycheva, N. S.

Organizations: Ministry of Education and Science of the Russian Federation [4.5510.2017/BCh]

It is shown that linear-dendritic block copolymers poly(N-isopropylacrylamide)-block-polyphenylenegermane can be prepared by the polymerization of N-isopropylacrylamide in the presence of bis(pentafluorophenyl)germane followed by activated polycondensation with tris(pentafluorophenyl)germane. The properties of the dilute solutions and Langmuir monolayers of the functional polymers and the linear-dendritic block copolymers of N-isopropylacrylamide are studied.