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Low density polyethylene composites containing cellulose pulp fibers

Year: 2012

Journal: Composites Part B: Engineering 2012, 43 (4) pp 1873-1880, 20121211

Authors: Anamaria Sdrobis, Raluca Nicoleta Darie, Marian Totolin, Georgeta Cazacu, Cornelia Vasile

Organizations: Romanian Academy, “Petru Poni” Institute of Macromolecular Chemistry, Physical Chemistry of Polymers Department, 41A Grigore Ghica Voda Alley, 700487 Iasi, Romania

Unbleached and bleached Kraft cellulosepulpfibers modified with a long chain carboxylic acid, i.e. oleic acid in cold plasma conditions have been used as reinforcements in lowdensitypolyethylene (LDPE). The purpose of the modification is to enhance the interfacial adhesion between cellulose and matrix and to increase the dispersability. Compositescontaining up to 10 wt.% of untreated and modified cellulosepulpfibers with LDPE were prepared by melt mixing. The samples were characterized by processing behavior, mechanical and rheological properties, SEM, contact angle measurements, TGA and DSC. It was found that when the modified pulpfibers were incorporated into composites matrix, most of the properties have been improved.