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    Luminescent Organic Semiconducting Langmuir Monolayers

    Year: 2017

    Journal: ACS Appl. Mater. Interfaces, Volume 9, MAY 31, page 18078–18086

    Authors: Agina, Elena V.; Mannanov, Artur A.; Sizov, Alexey S.; Vechter, Olga; Borshchev, Oleg V.; Bakirov, Artem V.; Shcherbina, Maxim A.; Chvalun, Sergei N.; Konstantinov, Vladislav G.; Bruevich, Vladimir V.; Kozlov, Oleg V.; Pshenichnikov, Maxim S.; Paraschuk, Dmitry Yu.; Ponomarenko, Sergei A.

    Organizations: Russian Science Foundation [15-02-30031]

    Keywords: thiophene-phenylene co-oligomers; photoluminescence; Langmuir-Blodgett and Langmuir-Schaefer monolayers; OFETs; organic electronics

    In recent years, monolayer organic field-effect devices such as transistors and sensors have demonstrated their high potential. In contrast, monolayer electroluminescent organic field-effect devices are still in their infancy. One of the key challenges here is to create an organic material that self-organizes in a monolayer and combines efficient charge transport with luminescence. Herein, we report a novel organosilicon derivative of oligothiophenephenylene dimer D2-Und-PTTP-TMS (D-2, tetramethyldisiloxane; Und, undecylenic spacer; P, 1,4-phenylene; T, 2,5-thiophene; TMS, trimethylsilyl) that meets these requirements. The self-assembled Langmuir monolayers of the dimer were investigated by steady-state and time-resolved photoluminescence spectroscopy, atomic force microscopy, X-ray reflectometry, and grazing-incidence X-ray diffraction, and their semiconducting properties were evaluated in organic field-effect transistors. We found that the best uniform, fully covered, highly ordered monolayers were semiconducting. Thus, the ordered two-dimensional (2D) packing of conjugated organic molecules in the semiconducting Langmuir monolayer is compatible with its high-yield luminescence, so that 2D molecular aggregation per se does not preclude highly luminescent properties. Our findings pave the way to the rational design of functional materials for monolayer organic light-emitting transistors and other optoelectronic devices.
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