Contact
    Start Publications Plasma-induced physicochemical effects on a poly(amide) ...
    ←  Publication Finder
    Attension

    Plasma-induced physicochemical effects on a poly(amide) thin-film composite membrane

    Year: 2017

    Journal: Desalination, Volume 403, FEB 1, page 3–11

    Authors: Reis, Rackel; Dumee, Ludovic F.; Merenda, Andrea; Orbell, John D.; Schutz, Jurg A.; Duke, Mikel C.

    Organizations: Collaborative Research Network initiative of the Australian Department of Industry; National Centre of Excellence in Desalination Australia - Australian Government through the National Urban Water and Desalination Plan

    Keywords: Plasma gas surface modification; Hydrophilicity control; Surface texturation; Flux enhancement; Thin film composite membrane

    Helium and water gas plasma were used to modify the surface morphology and chemistry of commercial thin film composite membranes. Such surface treatment is a convenient tool to alter performance of the membranes and subsequently reduce interactions with contaminants in solution. Plasma reactions such as etching and re-deposition resulted in surface functionalization and texturation which were correlated with membrane flux and salt rejection changes. Investigations conducted using atomic force microscopy revealed morphology alterations which were apparent as either smoother surfaces or rougher surfaces. While the smoothing was attributed to a re-deposition of polymer material, which originated most likely from vaporization of surface polymer, the roughening was a result from balanced plasma surface reactions. The beneficial etching can occur under certain conditions when helium is used in conjunction with low excitation power, which resulted in flux enhancements up to 66% (i.e. from 30 L.m(-2).h(-1) to 50 L.m(-2).h(-1)) with 98% rejection. The hydrophilicity was dramatically increased from 46.6 degrees to as low as 8.9 degrees after 5 min of helium plasma duration. The impact that plasma treatments have on the nascent structure was discussed in order to highlight its application as a convenient tool to functionalize the surface of thin film composite membranes. (C) 2016 Elsevier B.V. All rights reserved.
    View publication