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Preparation and Characterization of Soybean Oil-Based Polyurethanes for Digital Doming Applications

Year: 2017

Journal: Materials, Volume 10, AUG

Authors: Pantone, Vincenzo; Laurenza, Amelita Grazia; Annese, Cosimo; Comparelli, Roberto; Fracassi, Francesco; Fini, Paola; Nacci, Angelo; Russo, Antonella; Fusco, Caterina; D'Accolti, Lucia

Organizations: Regione Puglia MIUR PON Ricerca e Competitivita [Avviso 254/Ric., PONa3 00369, PON03PE_00004_1]; "MAIND" MAteriali eco-innovativi e tecnologie avanzate per l'INDustria Manifatturiera e delle costruzioni; Salvatore Pepe for fund "PIANI di SVILUPPO INDUSTRIALI attraverso PACCHETTI INTEGRATI di AGEVOLAZIONE (PIA) Regione Basilicata codice progetto [227179]

Keywords: catalysis; soybean oil; bio-based polyurethane; doming application

Polyurethane-resin doming is currently one of the fastest growing markets in the field of industrial graphics and product identification. Semi-rigid bio-based polyurethanes were prepared deriving from soybean oil as a valuable alternative to fossil materials for digital doming and applied to digital mosaic technology. Bio-resins produced can favorably compete with the analogous fossil polymers, giving high-quality surface coatings (ascertained by SEM analyses). In addition, polyurethane synthesis was accomplished by using a mercury-and tin-free catalyst (the commercially available zinc derivative K22) bringing significant benefits in terms of cost efficiency and eco-sustainability.