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Simple Green Approach to Reinforce Natural Rubber with Bacterial Cellulose Nanofibers

Year: 2013

Journal: Biomacromolecules, 2013, 14 (8), pp 2667–2674, 20131119

Authors: Eliane Trovatti 1 2, Antonio J. F. Carvalho 2, Sidney J. L. Ribeiro 3, and Alessandro Gandini * 1 2

Organizations: 1 † Instituto de Química de São Carlos, Universidade de São Paulo, PB 780, 13560-970, São Carlos, SP, Brazil, 2 ‡ Departamento de Engenharia de Materiais/Escola de Engenharia de São Carlos, Universidade de São Paulo, 13566-590, São Carlos, SP, Brazil, 3 § Instituto de Química, Universidade Estadual Paulista Júlio de Mesquita Filho, UNESP, 14801-970, Araraquara, SP, Brazil

Natural rubber (NR) is a renewable polymer with a wide range of applications, which is constantly tailored, further increasing its utilizations. The tensile strength is one of its most important properties susceptible of being enhanced by the simple incorporation of nanofibers. The preparation and characterization of natural-rubber based nanocomposites reinforced with bacterial cellulose (BC) and bacterial cellulose coated with polystyrene (BCPS), yielded high performance materials. The nanocomposites were prepared by a simple and green process, and characterized by tensile tests, dynamical mechanical analysis (DMA), scanning electron microscopy (SEM), and swelling experiments. The effect of the nanofiber content on morphology, static, and dynamic mechanical properties was also investigated. The results showed an increase in the mechanical properties, such as Young’s modulus and tensile strength, even with modest nanofiber loadings.