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    Stability of kaolin dispersion in the presence of lignin-acrylamide polymer

    Year: 2018

    Journal: Appl. Clay Sci., Volume 158, JUN 15, page 72–82

    Authors: Hasan, Agha; Fatehi, Pedram

    Organizations: NSERC [CRDCPJ434805-12]; Canada Foundation for Innovation (CFI) [33671]; Ontario Research Fund [33671]; Canada Research Chairs program; NOHFC [8320002]; FPInnovations

    Keywords: Lignin; Kaolin; Dispersion; Stability; Hydrodynamic size; Acrylamide

    Dispersion of kaolin in aqueous systems is important in many industries including ceramics, chemicals, pharmaceuticals and paints. In this work, kraft lignin-acrylamide (KAM) polymers were produced via polymerizing kraft lignin and acrylamide (AM) monomer with different molar masses and charge densities, and they were used for stabilizing kaolin dispersion at varied pHs. The surface tension and contact angle studies demonstrated that KAM improved the surface hydrophilicity of kaolin mineral particles. Among KAM polymers (KAM-1, KAM-2 and KAM-3), KAM-3 with the highest molar mass (M-w) of 97,000 g/mol and charge density of -2.1 meq/g had the highest adsorption of 2.16 mg/g onto kaolin mineral particles. It was also found that KAM adsorption on kaolin mineral particles was pH dependent with KAM adsorption decreasing with increasing pH from 4 to 10. Generally, increasing ionic strength enhanced the adsorption of KAM on kaolin mineral particles. Salt reduced electrostatic repulsion between the anionic KAM polymers and the negatively charged kaolin mineral particles and facilitated the adsorption. Relationship between zeta potential and relative turbidity of kaolin dispersion was developed at different levels of KAM adsorption. KAM (especially KAM-3) increased the volume fraction of kaolin mineral particles in the dispersion. It also improved the stability of kaolin dispersion, and the impact was more noticeable at pH 10. Treating the dispersion with KAM was more effective than mechanical stirring in stabilizing kaolin mineral particles.
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