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    Adsorption-assisted transport of water vapour in super-hydrophobic membranes filled with multilayer graphene platelets

    Year: 2019

    Journal: Nanoscale, Volume 11, JUN 28, page 11521–11529

    Authors: Gontarek, E.; Macedonio, F.; Militano, F.; Giorno, L.; Lieder, M.; Politano, A.; Drioli, E.; Gugliuzza, A.

    Organizations: Italian Ministry of Foreign Affairs and International CooperationMinistry of Foreign Affairs and International Cooperation (Italy)

    The effects of confinement of multilayer graphene platelets in hydrophobic microporous polymeric membranes are here examined. Intermolecular interactions between water vapour molecules and nanocomposite membranes are envisaged to originate assisted transport of water vapour in membrane distillation processes when a suitable filler-polymer ratio is reached. Mass transport coefficients are estimated under different working conditions, suggesting a strong dependence of the transport on molecular interactions. Remarkably, no thermal polarization is observed, although the filler exhibits ultrahigh thermal conductivity. In contrast, enhanced resistance to wetting as well as outstanding mechanical and chemical stability meets the basic requirements of water purification via membrane distillation. As a result, a significant improvement of the productivity-efficiency trade-off is achieved with respect to the pristine polymeric membrane when low amounts of platelets are confined in spherulitic-like PVDF networks.
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