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    Bijel rheology reveals a 2D colloidal glass wrapped in 3D

    Year: 2022

    Journal: Soft Matter, Volume 18, JUN 8, page 4227–4238

    Authors: Ching, Herman; Mohraz, Ali

    Organizations: NASA Research Opportunities in Complex Fluids and Macromolecular Biophysics Program [80NSSC18K1554, 80NSSC21K0897]; UCI Edwards Lifesciences Foundation Cardiovascular Innovation [1S10OD025064]; National Science Foundation through the UC Irvine Materials Research Science and Engineering Center [DMR-2011967]

    We present rheological evidence demonstrating the glass-like nature of bicontinuous interfacially jammed emulsion gels (bijels). Under small amplitude oscillatory shear, bijels exhibited rheological signatures akin to alpha and beta relaxation that are also invariable to interfacial tension changes, behaviors which are reminiscent of caged particle dynamics found in colloidal glasses, and well described by a previously reported adaptation of mode-coupling theory for colloidal glass rheology. Guided by their rheological signatures and supported by particle detachment and attraction energy approximations, we rationalize that bijels can be represented as 2-dimensional (2D) colloidal glasses that percolate in 3-dimensional (3D) space, and attractive interactions are not required for their stability. To provide further support for this conjecture, we qualitatively compare the rheology of bijels and a capillary suspension that is stabilized by strong, rigid capillary bridges between the particles, beyond their limit of linear viscoelasticity. Our results demonstrate that the strong adsorption of particles to the continuous interface and the lack of strong attractive interparticle forces enable recovery by interfacial tension into new jammed configurations after shear deformation. These behaviors are qualitatively different from those in the capillary suspension, where the breaking of attractive interparticle bonds results in dramatic changes to the microstructure and rheology over a narrow range of shear amplitudes. Our findings unveil bijels as 2D colloidal glasses weaving in 3D space and establish that interparticle attractions are not required for stability in bijels, and interfacial jamming alone is sufficient to impart viscoelasticity and gel-like rheology to these materials.
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