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    Bismuth oxyformate microspheres assembled by ultrathin nanosheets as an efficient negative material for aqueous alkali battery

    Year: 2023

    Journal: Journal of Colloid and Interface Science, Volume 639, 2023-06-01

    Authors: Chang, Jiuli; Liang, Wenfang; Xu, Fang; Wu, Dapeng; Jiang, Kai; Wang, Gongke; Gao, Zhiyong

    Keywords: Aqueous alkali battery; Bismuth oxyformate; Faradaic reaction; Hierarchical structure; Negative electrode

    A negative electrode with high capacity and rate capability is essential to match the capacity of a positive electrode and maximize the overall charge storage performance of an aqueous alkali battery (AAB). Due to the 3-electron redox reactions within a wide negative potential range, bismuth (Bi)-based compounds are recognized as efficient negative electrode materials. Herein, hierarchically structured bismuth oxyformate (BiOCOOH) assembled by ultrathin nanosheets was prepared by a solvothermal reaction for application as negative material for AAB. Given the efficient ion diffusion channels and sufficient exposure of the inner surface area, as well as the pronounced 3-electron redox activity of Bi species, the BiOCOOH electrode offered a high specific capacity (Cs, 229 ± 4 mAh g−1 at 1 A g−1) and superior rate capability (198 ± 6 mAh g−1 at 10 A g−1) within 0 ∼ −1 V. When pairing with the Ni3S2-MoS2 battery electrode, the AAB delivered a high energy density (Ecell, 217 mWh cm−2 at a power density (Pcell) of 661 mW cm−2), showing the potential of such a novel BiOCOOH negative material in battery-type charge storage.
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