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    Design and Tuning of Nanofluids Applied to Chemical Enhanced Oil Recovery Based on the Surfactant-Nanoparticle-Brine Interaction: From Laboratory Experiments to Oil Field Application

    Year: 2020

    Journal: Nanomaterials, Volume 10, AUG

    Authors: Franco, Carlos A.; Giraldo, Lady J.; Candela, Carlos H.; Bernal, Karla M.; Villamil, Fabio; Montes, Daniel; Lopera, Sergio H.; Franco, Camilo A.; Cortes, Farid B.

    Organizations: Ecopetrol S.A.

    Keywords: capillary number; CEOR; field trial; interfacial tension; nanofluids; surfactant flooding

    The primary objective of this study is to develop a novel experimental nanofluid based on surfactant-nanoparticle-brine tuning, subsequently evaluate its performance in the laboratory under reservoir conditions, then upscale the design for a field trial of the nanotechnology-enhanced surfactant injection process. Two different mixtures of commercial anionic surfactants (SA and SB) were characterized by their critical micelle concentration (CMC), density, and Fourier transform infrared (FTIR) spectra. Two types of commercial nanoparticles (CNA and CNB) were utilized, and they were characterized by S-BET, FTIR spectra, hydrodynamic mean sizes (dp(50)), isoelectric points (pH(IEP)), and functional groups. The evaluation of both surfactant-nanoparticle systems demonstrated that the best performance was obtained with a total dissolved solid (TDS) of 0.75% with the SA surfactant and the CNA nanoparticles. A nanofluid formulation with 100 mg center dot L(-1)of CNA provided suitable interfacial tension (IFT) values between 0.18 and 0.15 mN center dot m(-1)for a surfactant dosage range of 750-1000 mg center dot L-1. Results obtained from adsorption tests indicated that the surfactant adsorption on the rock would be reduced by at least 40% under static and dynamic conditions due to nanoparticle addition. Moreover, during core flooding tests, it was observed that the recovery factor was increased by 22% for the nanofluid usage in contrast with a 17% increase with only the use of the surfactant. These results are related to the estimated capillary number of 3 x 10(-5), 3 x 10(-4), and 5 x 10(-4)for the brine, the surfactant, and the nanofluid, respectively, as well as to the reduction in the surfactant adsorption on the rock which enhances the efficiency of the process. The field trial application was performed with the same nanofluid formulation in the two different injection patterns of a Colombian oil field and represented the first application worldwide of nanoparticles/nanofluids in enhanced oil recovery (EOR) processes. The cumulative incremental oil production was nearly 30,035 Bbls for both injection patterns by May 19, 2020. The decline rate was estimated through an exponential model to be -0.104 month(-1)before the intervention, to -0.016 month(-1)after the nanofluid injection. The pilot was designed based on a production increment of 3.5%, which was successfully surpassed with this field test with an increment of 27.3%. This application is the first, worldwide, to demonstrate surfactant flooding assisted by nanotechnology in a chemical enhanced oil recovery (CEOR) process in a low interfacial tension region.
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