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    Green Removal of DUV-Polarity-Modified PMMA for Wet Transfer of CVD Graphene

    Year: 2022

    Journal: Nanomaterials, Volume 12, NOV

    Authors: Jorudas, Justinas; Pashnev, Daniil; Kasalynas, Irmantas; Ignatjev, Ilja; Niaura, Gediminas; Selskis, Algirdas; Astachov, Vladimir; Alexeeva, Natalia

    Organizations: Research Council of Lithuania (Lietuvos mokslo taryba) through the Hybrid plasmonic components for THz range (T-HP) Grant - European Regional Development Fund [DOTSUT-184, 01.2.2-LMT-K-718-03-0096]

    Keywords: graphene; DUV; PMMA; THz-TDS

    To fabricate graphene-based high-frequency electronic and optoelectronic devices, there is a high demand for scalable low-contaminated graphene with high mobility. Graphene synthesized via chemical vapor deposition (CVD) on copper foil appears promising for this purpose, but residues from the polymethyl methacrylate (PMMA) layer, used for the wet transfer of CVD graphene, drastically affect the electrical properties of graphene. Here, we demonstrate a scalable and green PMMA removal technique that yields high-mobility graphene on the most common technologically relevant silicon (Si) substrate. As the first step, the polarity of the PMMA was modified under deep-UV irradiation at lambda = 254 nm, due to the formation of ketones and aldehydes of higher polarity, which simplifies hydrogen bonding in the step of its dissolution. Modification of PMMA polarity was confirmed by UV and FTIR spectrometry and contact angle measurements. Consecutive dissolution of DUV-exposed PMMA in an environmentally friendly, binary, high-polarity mixture of isopropyl alcohol/water (more commonly alcohol/water) resulted in the rapid and complete removal of DUV-exposed polymers without the degradation of graphene properties, as low-energy exposure does not form free radicals, and thus the released graphene remained intact. The high quality of graphene after PMMA removal was confirmed by SEM, AFM, Raman spectrometry, and by contact and non-contact electrical conductivity measurements. The removal of PMMA from graphene was also performed via other common methods for comparison. The charge carrier mobility in graphene films was found to be up to 6900 cm(2)/(V center dot s), demonstrating a high potential of the proposed PMMA removal method in the scalable fabrication of high-performance electronic devices based on CVD graphene.
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