Contact
    Start Publications Integration of Polypyrrole Electrode into Piezoelectric PVDF ...
    ←  Publication Finder
    Attension

    Integration of Polypyrrole Electrode into Piezoelectric PVDF Energy Harvester with Improved Adhesion and Over-Oxidation Resistance

    Year: 2019

    Journal: Polymers, Volume 11, JUN

    Authors: Baik, Kyungha; Park, Sohyun; Yun, Changsang; Park, Chung Hee

    Organizations: National Research Foundation (NRF) of Korea - Korean government (Ministry of Science and ICT) [NRF-2018R1A2B6003526, NRF-2016M3A7B4910940]

    Keywords: piezoelectricity; electroconductivity; flexibility; durability; electrode; energy harvester; polypyrrole; poly(vinylidene fluoride)

    Smart textiles for wearable devices require flexibility and a lightweight, so in this study, a soft polypyrrole (PPy) electrode system was integrated into a piezoelectric polyvinylidenefluoride (PVDF) energy harvester. The PVDF energy harvester integrated with a PPy electrode had the piezoelectric output voltage of 4.24-4.56 V, while the PVDF energy harvester with an additional aluminum-foil electrode exhibited 2.57 V. Alkaline treatment and chemical vapor deposition with n-dodecyltrimethoxysilane (DTMS) were employed to improve the adhesion between the PVDF and PPy and the resistance to over-oxidation in aqueous solutions. The PVDF film modified by an alkaline treatment could have the improved adhesion via the introduction of polar functional groups to its surface, which was confirmed by the ultrasonication. The surface hydrophobicity of the PPy electrode was enhanced by the DTMS coating, resulting in the improvement of the resistance to over-oxidation with a water contact angle of 111 degrees. Even with the hydrophobic coating, the electrodes remained electroconductive and continued to transfer an electric charge, maintaining the piezoelectricity of the PVDF film. The developed electrode-integrated energy harvester is expected to be applied to smart textiles because it offers the advantages of efficient piezoelectric generation, flexibility, and durability.
    View publication