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    Low permeable hydrophobic nanofibrilated cellulose films modified by dipping and heating processing technique

    Year: 2021

    Journal: Cellulose, Volume 28, FEB, page 1617–1632

    Authors: de Souza, Gustavo; Belgacem, Mohamed Naceur; Gandini, Alessandro; Carvalho, Antonio Jose Felix

    Organizations: Coordenacao de Aperfeicoamento de Pessoal de Nivel Superior-Brasil (CAPES) [001]; CNPq [03847/2019-0, 140249/2017-6]

    Keywords: Nanofibrilated cellulose (NFC); Films; Chemical modification; Blocked isocyanates; Barrier properties

    Nanofibrilated cellulose (NFC) films have potential to replace synthetic polymers as flexible films for packaging. However, NFC is hydrophilic and water acts as plasticizer decreasing the stiffness of the films and reducing its barrier effectiveness against water vapor and oxygen. Here we describe the surface modification of cellulose films with blocked diisocyanates through a dipping and heating process not requiring the previous drying of the materials. The reactions were conducted at 170 degrees C for a few minutes during which deblocking led to a new urethane bond formation with NFC surface hydroxyl groups, thus hydrophobizing the films. A remarkable enhancement in water repellent properties was confirmed by water contact angles higher than 110 degrees and water vapor transmission rate (WVTR) of 40 g/m(2) day, which is very low when compared to similar materials, representing a reduction of 74% with respect to the non- modified films. [GRAPHICS] .
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