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    Metasurface-Enhanced Raman Spectroscopy (mSERS) for Oriented Molecular Sensing

    Year: 2022

    Journal: ACS Appl. Mater. Interfaces, Volume 14, JUL 20, page 32598–32607

    Authors: Zeng, Yuan; Ananth, Riddhi; Dill, Tyler J.; Rodarte, Andrea; Rozin, Matthew J.; Bradshaw, Nathan; Brown, Eric R.; Tao, Andrea R.

    Organizations: San Diego Nanotechnology Infrastructure (NSF) [ECCS-2025752]; UC San Diego MRSEC (NSF) [DMR-2011924]; NSF [DMR-2011924, CHE-1807891]

    Keywords: colloids; plasmonic; metasurface; chemical sensing; SERS

    Surface-enhanced Raman spectroscopy (SERS) is a widely used sensing technique for ultrasensitivity chemical sensing, biomedical detection, and environmental analysis. Because SERS signal is proportional to the fourth power of the local electric field, several SERS applications have focused on the design of plasmonic nanogaps to take advantage of the extremely strong near-field enhancement that results from plasmonic coupling, but few designs have focused on how SERS detection is affected by molecular orientation within these nanogaps. Here, we demonstrate a nanoparticle-on-metal metasurface designed for near-perfect optical absorption as a platform for Raman detection of highly oriented molecular analytes, including two-dimensional materials and aromatic molecules. This metasurface platform overcomes challenges in nanoparticle aggregation, which commonly leads to low or fluctuating Raman signals in other colloidal nanoparticle platforms. Our metasurface-enhanced Raman spectroscopy (mSERS) platform is based on a colloidal Langmuir-Schaefer deposition, with up to 32% surface coverage density of nanogaps across an entire sensor chip. In this work, we perform both simulations of the local electric field and experimental characterization of the mSERS signal obtained for oriented molecular layers. We then demonstrate this mSERS platform for the quantitative detection of the drinking-water toxin polybrominated diphenyl ether (BDE-15), with a limit of detection of 0.25 mu M under 530 mu W excitation. This detection limit is comparable to other SERS-based sensors operating at laser powers over 3 orders of magnitude higher, indicating the promise of our mSERS platform for nondestructive and low-level analyte detection.
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