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    Micellization and antimicrobial properties of N-alkyl-(2-hydroxypropyl)morpholinium bromides

    Year: 2021

    Journal: J. Mol. Liq., Volume 335, AUG 1

    Authors: Rahimov, Ravan A.; Ahmadova, Gulnara A.; Huseynova, Khuraman A.; Muradova, Sevda A.; Mammadov, Rustam Kh; Rustamova, Inara, V; Qasimova, Fatma, I; Zubkov, Fedor, I

    Organizations: RUDN University Strategic Academic Leadership Program; Institute of Petrochemical Processes of National Academy of Sciences of Azerbaijan

    Keywords: Cationic surfactant; Micellization; Surface tension; Adsorption; Antimicrobial

    New ionic-liquid cationic surfactants have been synthesized on the basis of alkyl (C-9, C-10, C-12, C-14) bromides and 1-(4-morpholinyl)-2-propanol. Surface activity and specific electroconductivity of aqueous solutions of the obtained surfactants have been studied by tensiometric and conductometric methods. Depending on the length of the alkyl chain, the values of critical micellization concentration (CMC), maximum adsorption (Gamma(max)), area of minimal cross-sectional surface of polar group of the surfactant (A(min)), adsorption efficiency (pC(20)), surface pressure (pi(CMC)), binding degree of the counter-ion (beta), changes of Gibbs free energies of micellization and adsorption processes (Delta G(mic) and Delta G(ad)) have been determined. Antimicrobial properties of the synthesized ionic-liquid surfactants have been studied on the example of different bacteria and fungus. (C) 2021 Elsevier B.V. All rights reserved.
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