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    Mitigation of bidirectional solute flux in forward osmosis via membrane surface coating of zwitterion functionalized carbon nanotubes

    Year: 2019

    Journal: Environ. Int., Volume 131, OCT

    Authors: Zou, Shiqiang; Smith, Ethan D.; Lin, Shihong; Martin, Stephen M.; He, Zhen

    Organizations: Institute for Critical Technology and Applied Science, Virginia Tech; Water INTERface IGEP at Virginia Tech; Virginia Tech

    Keywords: Forward osmosis; Reverse solute flux; Forward solute flux; Zwitterion; Membrane modification

    Forward osmosis (FO) has emerged as a promising membrane technology to yield high-quality reusable water from various water sources. A key challenge to be solved is the bidirectional solute flux (BSF), including reverse solute flux (RSF) and forward solute flux (FSF). Herein, zwitterion functionalized carbon nanotubes (Z-CNTs) have been coated onto a commercial thin film composite (TFC) membrane, resulting in BSF mitigation via both electrostatic repulsion forces induced by zwitterionic functional groups and steric interactions with CNTs. At a coating density of 0.97 gm(-2), a significantly reduced specific RSF was observed for multiple draw solutes, including NaCl (55.5% reduction), NH4H2PO4 (83.8%), (NH4)(2)HPO4 (74.5%), NH4Cl (70.8%), and NH4HCO3 (61.9%). When a synthetic wastewater was applied as the feed to investigate membrane rejection, FSF was notably reduced by using the coated membrane with fewer pollutants leaked to the draw solution, including NH4+-N (46.3% reduction), NO2--N (37.0%), NO3--N (30.3%), K+ (56.1%), PO43--P (100%), and Mg2+ (100%). When fed with real wastewater, a consistent water flux was achieved during semi-continuous operation with enhanced fouling resistance. This study is among the earliest efforts to address BSF control via membrane modification, and the results will encourage further exploration of effective strategies to reduce BSF.
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