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    Novel Design of Superhydrophobic and Anticorrosive PTFE and PAA plus beta - CD Composite Coating Deposited by Electrospinning, Spin Coating and Electrospraying Techniques

    Year: 2022

    Journal: Polymers, Volume 14, OCT

    Authors: Vicente, Adrian; Rivero, Pedro J.; Urdiroz, Unai; Garcia, Paloma; Mora, Julio; Palacio, Jose F.; Javier Palomares, F.; Rodriguez, Rafael

    Organizations: MCIN/AEI [RTI2018-096262-B-C41-MAITAI, PRE2019-090656, PJUPNA1929]; ERDF A way of making Europe; ESF Investing in your future; BEI

    Keywords: electrospinning; electrospraying; PTFE; PAA plus beta-CD; corrosion resistance; super hydrophobic; low water roll-off angle; adhesion resistance

    A superhydrophobic composite coating consisting of polytetrafluoroethylene (PTFE) and poly(acrylic acid)+ beta-cyclodextrin (PAA + beta-CD) was prepared on an aluminum alloy AA 6061T6 substrate by a three-step process of electrospinnig, spin coating, and electrospraying. The electrospinning technique is used for the fabrication of a polymeric binder layer synthesized from PAA + beta-CD. The superhydrophilic characteristic of the electrospun PAA + beta-CD layer makes it suitable for the absorption of an aqueous suspension with PTFE particles in a spin-coating process, obtaining a hydrophobic behavior. Then, the electrospraying of a modified PTFE dispersion forms a layer of distributed PTFE particles, in which a strong bonding of the particles with each other and with the PTFE particles fixed in the PAA + beta-CD fiber matrix results in a remarkable improvement of the particles adhesion to the substrate by different heat treatments. The experimental results corroborate the important role of obtaining hierarchical micro/nano multilevel structures for the optimization of superhydrophobic surfaces, leading to water contact angles above 170 degrees, very low contact angle of hysteresis (CAH = 2 degrees) and roll-off angle (alpha(roll-off) < 5 degrees). In addition, a superior corrosion resistance is obtained, generating a barrier to retain the electrolyte infiltration. This study may provide useful insights for a wide range of applications.
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