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    Real-time changes of the adsorption process and conformation of marine dissolved organic matters on the solid-liquid interface

    Journal: Chemosphere, Volume 289, FEB

    Authors: Wu, Changyong; Fu, Liya; Wang, Yue; Wan, Chunli

    Organizations: National Key R&D Program of China [2020YFC1806302]; National Natural Science Foundation of China [42077213, 41977315]

    Keywords: Marine dissolved organic matters (MDOMs); Quartz crystal microbalance with dissipation (QCM-D); Adsorption; Viscoelasticity; Acid polysaccharides

    In this study, the adsorption characteristics of marine dissolved organic matters (MDOMs) on the solid-liquid interface in the coastal waters was investigated. The results showed that the organic macromolecules with adsorption ability in MDOMs are not rigid molecules. However, the macromolecules have viscoelasticity properties. At different dilution ratios, the MDOMs adsorption process includes rapid (0-200 s) and slow adsorption (200 s later) periods. MDOMs adsorption in the solid-liquid interface is a dynamic process in which adsorption and hydration occur simultaneously. MDOMs concentration is an important driving force for adsorption. The three macromolecules of acid polysaccharides, protein-like, and polycarboxylate-type humic acids in MDOMs are rich in functional groups and they have the ability to absorb to solid surface. Acidic polysaccharides exhibit a sustained adsorption ability, while the adsorption of other macromolecules occurred only in the initial rapid adsorption period. In addition, the acid polysaccharides show weak thixotropy during the adsorption process. It would cause the stretching of macromolecular structure of the adsorption layer, enhancing the hydration of the adsorption layer. The study shows the adsorption process of MDOMs at the solid-liquid interface and the structural characteristics of the adsorption layer. It can provide helpful information for the inhibition and removal of MDOMs pollution during the actual development of marine resources.
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