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    Rhodamine B-decorated poly(hydroxypropyl acrylate) and their effects on the self-assembly of breath figure arrays

    Year: 2018

    Journal: Polym. Bull., Volume 75, JUL, page 2887–2900

    Authors: Liu, Qian; Yan, Chun-Na; Xu, Xin-Meng; Wang, Li-Ping; Li, Guang

    Organizations: Shandong Province higher education science and technology program [J16LA01]; Natural Science Foundation of China [51503094]; Natural Science Foundation of Shandong Province [ZR2015BQ002]; Science and Technology Innovation Fund of Liaocheng University [26312161932]

    Keywords: Breath figure method; Honeycomb-structured porous films; Hydrophilic copolymers; Fluorescent property

    Novel poly(hydroxypropyl acrylate)-co-poly(hydroxypropyl acrylate)-rhodamine B (PHPA-co-PHPA-RhB) hydrophilic copolymers were synthesized via radical polymerization in this paper. And then the honeycomb-structured porous films were fabricated by dropping the (PHPA-co-PHPA-RhB) copolymers and PS solution on glass substrates by breath figure method (BFM). The effects of solvent, hydrophilic copolymers' molecular weight, the proportion of hydrophilic copolymers and hydrophobic polymers on the formation of porous films were investigated. The porous films were characterized by scanning electron microscopy (SEM), atomic force microscopy (AFM), spectrofluorometer and confocal laser scanning microscope (CLSM). The results show that PHPA-co-PHPA-RhB and PS solutions can form regular honeycomb porous films; the average diameter of the films pore decreases with the proportion of hydrophobic polystyrene increased. Similar regular was also found when the molecular weight of PHPA-co-PHPA-RhB was enhanced. Furthermore, the fluorescence properties of the porous films were also investigated in this study.
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