Contact
    Start Publications Synthesis, Characterization, and Properties of Highly ...
    ←  Publication Finder
    Attension

    Synthesis, Characterization, and Properties of Highly Hydrophilic Polyaniline Sulfonic Acid

    Year: 2020

    Journal: Russ. J. Gen. Chem., Volume 90, JUN, page 1055–1061

    Authors: Wu, Zhiqiang; Wang, Gang; Yuan, Shuo; Zhan, Haijuan; Liu, Wanyi; Bi, Shuxian; Li, Heping; Ma, Baojun; Sun, Yanyan

    Organizations: Major Innovation Projects for Building First-class Universities in China's Western Region [ZKZD 2017003]; National First-rate Discipline Construction Project of Ningxia [NXYLXK2017A04]; National Natural Science Foundation of ChinaNational Natural Science Foundation of China (NSFC) [21862013]

    Keywords: sulfonated polyaniline; nano hollow spherical; solid acid; hydrophilicity; BIMs

    A hollow spherical highly hydrophilic polyaniline sulfonic acid catalyst has been successfully prepared by emulsion polymerization and SO(3)liquid sulfonation using modified polystyrene microspheres (PS) as a template. Acid value of the solid acid catalyst is 2.516 mmol/g. Morphology, structure and thermal stability of the catalyst have been studied by XRD, SEM, TEM, FT-IR, X-ray photoelectron spectroscopy (XPS), and TGA. It has been proven that doping and sulfonation of PANI and SO(3)lead to new molecule that retains the PANI matrix material. In view of close structure-activity relationship, it has been applied to the efficient synthesis of bis(indolyl)methanes (BIMs) in water-ethanol phase.
    View publication