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    Tb(III) complexes with 1-phenyl-3-methyl-4-stearoyl-pyrazol-5-one as a material for luminescence Langmuir-Blodgett films

    Year: 2018

    Journal: J. Coord. Chem., Volume 71, DEC 17, page 4228–4236

    Authors: Shul'gin, Victor; Pevzner, Natalya; Gusev, Alexey; Sokolov, Michail; Panyushkin, Victor; Devterova, Julia; Kirillov, Kirill; Martynenko, Igor; Linert, Wolfgang

    Organizations: Russian Ministry of Education and Science [10.1622.2017/PP, 16.5903.2017/8.9]

    Keywords: Terbium complexes; 4-stearoylpyrazol-5-one; Langmuir-Blodgett film; luminescence

    Synthesis and properties of new luminescent amphiphilic Tb(III) complexes [TbL3 center dot 2H(2)O]center dot 3H(2)O, TbL3 center dot bipy, [H3O][TbL4]center dot 6H(2)O and [H3O][TbL ' L-3]center dot H2O, where HL is 1-phenyl-3-methyl-4-stearoylpyrazolone-5 and HL ' is 1-phenyl-3-methyl-4-formylpyrazolone-5, are reported. The complexes have been characterized by elemental and thermal analysis, FTIR and luminescence spectroscopy methods. Formation and properties of Langmuir-Blodgett films of the complexes are described.
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