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    Unmodified Clay Nanosheets at the Air-Water Interface

    Year: 2021

    Journal: Langmuir, Volume 37, JAN 12, page 160–170

    Authors: Michels-Brito, Paulo H.; Malfatti-Gasperini, Antonio; Mayr, Lina; Puentes-Martinez, Ximena; Tenorio, Romulo P.; Wagner, Daniel R.; Knudsen, Kenneth D.; Araki, Koiti; Oliveira, Rafael G.; Breu, Josef; Cavalcanti, Leide P.; Fossum, Jon Otto

    Organizations: NTNU Nanolab [81771176]; Research Council of NorwayResearch Council of Norway [250619, 280643, 250728, 221860/F60]; Research Council of Brazil (CNPq)Conselho Nacional de Desenvolvimento Cientifico e Tecnologico (CNPQ)Fundacao de Apoio a Pesquisa do Distrito Federal (FAPDF) [432279/2016-4]; Universidad de Boyaca; LNLS [20180114]; Centro de Investigaciones en Quimica Biologica de Cordoba; German Science Foundation (DFG)German Research Foundation (DFG) [SFB 840]

    Quasi-two-dimensional (2D) nanolayers, such as graphene oxide or clay layers, adhere to gas-liquid or liquid-liquid interfaces. Particularly, clays are of wide general interest in this context because of their extensive and crucial use as Pickering emulsion stabilizers, as well as for their ability to provide colloidosome capsules. So far, clays could only be localized at oil-water or air-saline-water interfaces in aggregated states, while our results now show that clay nanosheets without any modification can be located at air-deionized-water interfaces. The clay mineral used in the present work is synthetic fluorohectorite with a very high aspect ratio and superior quality in homogeneity and charge distribution compared to other clay minerals. This clay mineral is more suitable for achieving unmodified clay anchoring to fluid interfaces compared to other clay minerals used in previous works. In this context, we studied clay nanosheet organization at the air-water interface by combining different experimental methods: Langmuir-Blodgett trough studies, scanning electron microscopy (SEM) studies of film deposits, grazing-incidence X-ray off-specular scattering (GIXOS), and Brewster angle microscopy (BAM). Clay films formed at the air-water interface could be transferred to solid substrates by the Langmuir-Schaefer method. The BAM results indicate a dynamic equilibrium between clay sheets on the interface and in the subphase. Because of this dynamic equilibrium, the Langmuir monolayer surface pressure does not change significantly when pure clay sheets are spread on the liquid surface. However, also, GIXOS results confirm that there are clay nanosheets at the air-water interface. In addition, we find that clay sheets modified by a branched polymer are much more likely to be confined to the interface.
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