Start Publications Assembly of Poly(dopamine) Films Mixed with a Nonionic Polymer
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Assembly of Poly(dopamine) Films Mixed with a Nonionic Polymer

Year: 2012

Journal: Langmuir, 2012, 28 (51), pp 17585–17592, 20130403

Authors: Yan Zhang 1 2, Bo Thingholm 2, Kenneth N. Goldie 3, Ryosuke Ogaki 2, and Brigitte Städler *2

Last authors: Brigitte Städler

Organizations: 1 State Key Laboratory for Modification of Chemical Fibers and Polymer Materials, College of Material Science and Engineering, Donghua University, Shanghai, People’s Republic of China 2 iNANO Interdisciplinary Nanoscience Centre, Aarhus University, Aarhus, Denmark 3 Center for Cellular Imaging & Nano Analytics, Biozentrum, University of Basel, Basel, Switzerland

Country: China, Denmark, Switzerland

Poly(dopamine) (PDA) coatings have recently attracted considerable interest for a variety of applications. Here, we investigate the film deposition of dopamine mixed with a nonionic polymer (i.e., poly(ethylene glycol) (PEG), poly(vinyl alcohol) (PVA), and poly(N-vinyl pyrrolidone) (PVP)) onto silica substrates using X-ray photoelectron spectroscopy and quartz crystal microbalance. Furthermore, we assess the possibility of coating silica colloids to yield polymer capsules and liposomes with these mixtures. We found that mixed PDA/PEG and PDA/PVA films are deposited without the need for a covalent linker such as an amine or thiol. We also discovered the first material, namely, PVP, that can suppress PDA film assembly. These fundamental findings give further insight into PDA film properties and contribute to establish PDA as a widely applicable coating.