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Characterization of solvent-spun polyester nanofibers

Year: 2011

Journal: Journal of Applied Polymer Science Volume 120, Issue 2, pages 759–769, 20111221

Authors: S. Duzyer1, A. Hockenberger1,*, E. Zussman2

Organizations: 1 Department of Textile Engineering, Uludag University, Bursa 16059, Turkey, 2 Faculty of Mechanical Engineering, Technion–Israel Institute of Technology, Haifa 32000, Israel

The aim of this study was to examine the properties of polyester nanofibers produced by the electrospinning method. Solvent-spun nanofibers with different concentrations of poly(ethylene terephthalate) (13, 16, and 20 wt %) were produced. The morphology and surface energy of the fibers were analyzed by scanning electron microscopy and contact angle measurements. Tensile testing, dynamic mechanical analysis, and differential scanning calorimetry were carried out to characterize the thermal and mechanical properties. X-ray diffraction and attenuated total reflection Fourier transform infrared spectroscopy tests were performed to analyze the microstructural properties. The results show that a nanoweb of the 16 wt % solution had better mechanical and thermal behaviors because of the increased molecular orientation in the amorphous structure and the narrower fiber diameter distribution in the web. © 2010 Wiley Periodicals, Inc. J Appl Polym Sci, 2011