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Conducting PEDOT–PSS composite films assembled by LB technique

Year: 2007

Journal: Colloids and Surfaces A: Physicochemical and Engineering Aspects, Volume 302, Issues 1-3, 20 July 2007, Pages 157-161, 20111221

Authors: Yajie Yang, Yadong Jiang, Jianhua Xua and Junsheng Yu

Organizations: State Key Lab of Electronic Thin Films & Integrated Devices, School of Optoelectronic Information, University of Electronic Science and Technology of China (UESTC), Chengdu 610054, PR China

The immobilization of conducting poly(3,4-ethylenedioxythiophene)–poly(styrene sulfonate) (PEDOT–PSS) nanoparticles by Langmuir–Blodgett (LB) technique has been reported. Composite films of ODA/PEDOT–PSS and ODA–SA/PEDOT–PSS were fabricated by LB inducing deposition method. The surface pressure (π)–area (A) isotherm of the composite monolayer at air/liquid interface was studied. The result shows that there is the intense electrostatic force between SO3-group of PSS and NH3+-group of aliphatic amine. The solid composite LB film was investigated by UV–vis spectrum, atomic force microscopy (AFM), X-ray photoelectron spectroscopy (XPS) and X-ray diffraction (XRD) method. The results show that ODA–SA/PEDOT–PSS had higher film-processing capability than ODA/PEDOT–PSS film. Electrostatic force between ODA and PEDOT–PSS was confirmed by XPS analysis. An intensity enhancement of S (2p) of PEDOT in composite LB films comparing with spin-coated PEDOT–PSS films was observed. Electrical characteristic of these composite LB films was measured and the conductive mechanism of composite films was also included.