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    Difference in hot carrier cooling rate between Langmuir-Blodgett and drop cast PbS QD films due to strong electron-phonon coupling

    Year: 2017

    Journal: Nanoscale, Volume 9, NOV 21, page 17133–17142

    Authors: Cao, Wenkai; Yuan, Lin; Patterson, Rob; Wen, Xiaoming; Tapping, Patrick C.; Kee, Tak; Veetil, Binesh Puthen; Zhang, Pengfei; Zhang, Zewen; Zhang, Qiuyang; Reece, Peter; Bremner, Stephen; Shrestha, Santosh; Conibeer, Gavin; Huang, Shujuan

    Organizations: Australian Government through the Australian Research Council (ARC); Australian Renewable Energy Agency (ARENA); NSW Government Science Leverage Fund

    The carrier dynamics of lead sulphide quantum dot (PbS QD) drop cast films and closely packed ordered Langmuir-Blodgett films are studied with ultra-fast femtosecond transient absorption spectroscopy. The photo-induced carrier temperature is extracted from transient absorption spectra and monitored as a function of time delay. The cooling dynamics of carriers in PbS QDs suggest a reduction of the carrier energy loss rate at longer time delays through the retardation of the longitudinal optical (LO) phonon decay due to partial heating of acoustic phonon modes. A slowed hot carrier cooling time up to 116 ps is observed in the drop cast film. A faster cooling rate was also observed in the highly compact Langmuir-Blodgett film due to the enhanced carrier-LO phonon coupling strength arising from the Coulombic interaction in neighboring QDs, which is verified by temperature dependent steady state PL measurements.
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