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Gamma irradiation assisted fungal degradation of the polypropylene/biomass composites

Year: 2016

Journal: Radiat. Phys. Chem.

Authors: Butnaru, E; Darie-Nita, RN; Zaharescu, T; Balaes, T; Tanase, C; Hitruc, G; Doroftei, F; Vasile, C

White-rot fungus Bjerkandera adusta has been tested for its ability to degrade some biocomposites materials based on polypropylene and biomass (Eucalyptus globulus, pine cones, and Brassica rapa). gamma-irradiation was applied to initiate the degradation of relatively inert polypropylene matrix. The degradation process has been studied by scanning electron microscopy, atomic force microscopy, infrared spectroscopy, contact angle measurements, rheological and chemiluminescence tests. These analyses showed that the polypropylene/biomass composites properties are worsen under the action of the selected microorganism. The formation of cracks and scrap particles over the entire matrix surface and the decrease of the complex viscosity values, as well as the dynamic moduli of gamma irradiated PP/biomass composite and exposed to Bjerkandera adusta fungus, indicate fungal efficiency in composite degradation. (C) 2016 Elsevier Ltd. All rights reserved.