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    High- and low-adhesive superhydrophobicity on the liquid flame spray-coated board and paper: structural effects on surface wetting and transition between the low- and high-adhesive states

    Year: 2013

    Journal: Colloid and Polymer Science, 2013, 291 (2), pp 447-455, 20130926

    Authors: Hannu Teisala, Mikko Tuominen, Mikko Aromaa, Milena Stepien, Jyrki M. Mäkelä, Jarkko J. Saarinen, Martti Toivakka, Jurkka Kuusipalo

    Organizations: Paper Converting and Packaging Technology, Department of Energy and Process Engineering, Tampere University of Technology, P.O. Box 589, FI-33101, Tampere, Finland; Aerosol Physics Laboratory, Department of Physics, Tampere University of Technology, P.O. Box 692, FI-33101, Tampere, Finland; Laboratory of Paper Coating and Converting, Center for Functional Materials, Abo Akademi University, Porthansgatan 3, FI-20500, Turku, Finland

    Surface wetting is an important and relevant phenomenon in several different fields. Scientists have introduced a large number of applications where special surface wetting could be exploited. Here, we study wetting phenomena on high- and low-adhesive superhydrophobic liquid flame spray (LFS)-generated TiO2 coatings on paper and pigment-coated board substrates using water–ethanol solution as a probe liquid. Submicrometer-scale air gaps, which exist on superhydrophobic surfaces below the liquid droplets, were more stable with the ethanol increment than the larger-scale micrometric air gaps. With the droplet ethanol concentration of 15 wt%, static contact angle as high as 155 ± 2° was measured on the LFS–TiO2-coated board. Transition from the low-adhesive wetting state to the high-adhesive state was demonstrated on the LFS–TiO2-coated paper. The LFS method enables efficient roll-to-roll production of surfaces with special wetting properties on economically viable board and paper substrate materials.