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On the influence of silicon oxide nanoparticles on the optical and surface properties of hybrid (inorganic–organic) barrier materials

Year: 2009

Journal: Thin Solid Films, Volume 517, Issue 23, 1 October 2009, Pages 6275-6279, 20111221

Authors: A. Laskarakis, S. Logothetidis, D. Georgiou, S. Amberg-Schwab and U. Weber

Organizations: Aristotle University of Thessaloniki, Department of Physics, Laboratory for Thin Films – Nanosystems and Nanometrology, GR-54124, Thessaloniki, Greece

One of the major scientific and technological challenges for the production of flexible organic electronic devices is the device protection against atmospheric molecule permeation, which causes corrosion reducing its operation and lifetime. In this work, Spectroscopic Ellipsometry has been implemented to investigate the influence of silicon dioxide nanoparticles on the optical properties of hybrid polymers. The spectra analysis revealed valuable information about the electronic and vibrational response as well as the cross-linking mechanisms of these materials. The correlation of the optical properties with the synthesis parameters and the barrier response will contribute towards their optimization in order to be used as high barrier coatings for flexible organic electronics applications.