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Study of adsorption kinetics of surfactants onto polyethersulfone membrane surface using QCM-D

Year: 2009

Journal: Desalination, Volume 247, Issues 1-3, October 2009, Pages 355-361, 20100827

Authors: Liua S.X. 1 *, Kim J.T. 2

Last authors: Jun-Tae Kim

Organizations: 1 Cereal Products and Food Science Research Unit, National Center for Agricultural Utilization Research, USDA, ARS, 1815 N. University Street, Peoria, IL 61604, USA 2 Department of Fiber Science and Apparel Design, Cornell University, 201 Martha Van Rensselaer Hall, Ithaca, NY 14853-4401, USA

Country: USA, US, United States of America

The adsorption kinetics of surfactants onto the crystal surface spin-coated with a thin layer of a model membrane material, polyethersulfone was monitored through measurements of frequency and dissipation shifts simultaneously using a quartz crystal microbalance with dissipation ( QCM-D) apparatus. In this study, the viscoelastic behaviors of the adsorbed surfactant layers of sodium laureth sulfate, cocamidopropyl betaine and their mixed solution (1:1) expressed through the dissipation parameters from the QCM-D measurements were used to deduce the structures of the adsorbed layers of the surfactants as a combinative result of characteristics of the surfactant and the hydrophobicity of the membrane surface.