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Superhydrophobic Behavior of a Perfluoropolyether Lotus-Leaf-like Topography

Year: 2006

Journal: Langmuir 22 (2006) 8576-8580, 20111221

Authors: Lei Zhang, Zhilian Zhou, Bin Cheng, Joseph M. DeSimone, and Edward T. Samulski

Organizations: Curriculum in Applied & Materials Sciences and Department of Chemistry, University of North Carolina at Chapel Hill, Chapel Hill, North Carolina 27599-3290

We demonstrate the fabrication of 2-D arrays of nanopillars made from perfluoropolyether derivatives using a porous anodic aluminum oxide membrane as a template. Pretexturing the aluminum prior to anodization enables one to engineer multiple morphological length scales and thereby synthesize a lotus-leaf-like topography. Both nanopillars on a flat surface and on a lotus-leaf-like topology exhibit superhydrophobicity, low contact angle hysteresis, and self-cleaning.