Triggered J-aggregation in Mixed Langmuir-Blodgett Films of Amphiphilic Spiropyran Having a Methoxy Group at the 5 ' Position and an Azobenzene Derivative

Here, we describe the formation of J-aggregates triggered by isomerization of an azobenzene derivative, N[p-[(p-dodecylphenylazo)phenyloxy]dodecylpyridinium bromide (AzP), in mixed Langmuir-Blodgett (LB) films that contain an amphiphilic spiropyran with a methoxy group at the 5' position, MeO-SP1822. Pure LB films of MeO-SP1822 consist of multilayer domains embedded in a monolayer. UV irradiation of the films causes the isomerization of MeO-SP1822 to its merocyanine form, MeO-MC1822. Pure LB films of AzP comprise finger-like domains and granular domains. Irradiating mixed films of MeO-SP1822 and AzP with alternating UV and visible light causes J-aggregation of MeO-MC1822, with the amount of J-aggregates reaching a maximum at a 1:1 molar ratio. J-aggregation occurs in flat finger-like structures originating in the AzP-rich granular domains that are located on top of the MeO-MC1822-rich multilayer domains. J-aggregates are also present under the AzP-rich granular domains, though these domains do not serve as nucleation sites for the finger-like structures. We propose that granular domains serving as nucleation sites are partially buried in the multilayer domains, whereas those triggering the J-aggregation of MeO-MC1822 under the granular domains are situated on top of the multilayer domains.