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Wine classification by taste sensors made from ultra-thin films and using neural networks

Year: 2004

Journal: Sensors and Actuators B 98 (2004) 77-82, 20111221

Authors: Antonio Riul Jr. , Humberto C. de Sousa , Roger R. Malmegrim , David S. dos Santos Jr. , Andre C.P.L.F. Carvalho , Fernando J. Fonseca , Osvaldo N. Oliveira Jr. , Luiz H.C. Mattoso

Organizations: a Depto de Fisica, Quimica e Biologia, FCT-UNESP, CP 467,19060-900 Presidente Prudente, SP, Brazil b Instituto de Cîencias Matemáticas e de Computao, USP, CP 668, 13560-970 Sao Carlos, SP, Brazil c EMBRAPA Instrumentao Agropecuaria, CP 741, 13.560-970 Sao Carlos, SP, Brazil d Instituto de Fisica de Sao Carlos, USP, CP 369, CEP 13.560-970 Sao Carlos, SP, Brazil e Escola Politecnica da Universidade de Sao Paulo, USP, CEP 05508-900 Sao Paulo, SP, Brazil

This paper reports on a sensor array able to distinguish tastes and used to classify red wines. The array comprises sensing units made from Langmuir-Blodgett (LB) films of conducting polymers and lipids and layer-by-layer (LBL) films from chitosan deposited onto gold interdigitated electrodes. Using impedance spectroscopy as the principle of detection, we show that distinct clusters can be identified in principal component analysis (PCA) plots for six types of red wine. Distinction can be made with regard to vintage, vineyard and brands of the red wine. Furthermore, if the data are treated with artificial neural networks (ANNs), this "artificial tongue" can identify wine samples stored under different conditions. This is illustrated by considering 900 wine samples, obtained with 30 measurements for each of the five bottles of the six wines, which could be recognised with 100% accuracy using the algorithms Standard Backpropagation and Backpropagation momentum in the ANNs.