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    Electrostatically self-assembled chitosan derivatives working as efficient cathode interlayers for organic solar cells

    Year: 2017

    Journal: Nano Energy, Volume 34, APR, page 164–171

    Authors: Zhang, Kai; Xu, Rongguo; Ge, Wenjiao; Qi, Meng; Zhang, Guangzhao; Xu, Qing-Hua; Huang, Fei; Cao, Yong; Wang, Xiaohui

    Keywords: Environmentally-friendly; Chitosan; Electron transport layers; Self-assembly; Organic solar cells

    In this work, we employed chitosan, which is the second most abundant biomass on earth after cellulose, and its derivatives as cathode interlayer (instead of substrate) materials in inverted organic solar cells (OSCs) by employing electrostatic Layer-by-Layer (eLbL) self-assembly technique. It was found that the eLbL self assembly technique was a suitable strategy to obtain continuous films with full surface coverage, uniformity and controlled thickness under nanometer scale. What's more, due to the highly ordered layer-by-layer structure, both interfacial dipoles and molecular dipoles were formed and utilized to decrease the work function of the electrode and enhance device performance. With optimized chitosan eLbL films as cathode interlayer, inverted OSCs exhibited a power conversion efficiency (PCE) of 9.34%, which was approximately a 200% improvement over cells with no cathode interlayer. Moreover, the chitosan eLbL films can be utilized to improve the PCE of thick active layer (210 nm) OSC5 to 10.18%.
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