Hydrophobic tungsten oxide-based mesh modified with hexadecanoic branches for efficient oil/water separation
Year: 2022
Journal: J. Water Process. Eng., Volume 49, OCT
Authors: Said, Ahmad; Al Abdulgader, Hasan; Alsaeed, Duaa; Drmosh, Q. A.; Baroud, Turki N.; Saleh, Tawfik A.
Keywords: Clean technology; Water treatment; Pollutants removal; Oil; Adsorption
The development of facile and highly efficient materials for oil/water separation has recently attracted significant attention. Herein, a novel approach for the development of tungsten oxide-based meshes modified with palmitic acid (hexadecanoic) is reported. The stainless steel meshes were first coated with tungsten oxide thin film using a direct current (DC) sputtering system followed by post-annealing treatments at different temperatures specifically at room temperature, 200, 400, 600, and 800 degrees C. After that, the as-fabricated films were chemically functionalized with palmitic acid. The fabricated samples were then characterized using SEM-EDX, XRD, and contact angle measurement. Their separation efficiency towards oil/water separation was evaluated. Excellent reproducibility was obtained by the functionalized tungsten-oxide film treated at 600 degrees C. The same sample showed excellent flux (up to 30,000 L.m(-2).h(-1)) with excellent separation efficacy of around 98.0 +/- 1.5 %. The modified mesh showed excellent separation efficiency even with saline mixtures. The reported facile approach can pave the way for more practical utilization of coating nanomaterials for oil/water separation.
