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    In-situ growth of porous Cu 3 (BTC) 2 on cellulose nanofibrils for ultra-low dielectric films with high flexibility

    Year: 2022

    Journal: J. Mater. Sci. Technol., Volume 112, JUN 10, page 202–211

    Authors: Liu, Rui; He, Xiang; Miao, Miao; Cao, Shaomei; Feng, Xin

    Organizations: Science and Technology Commission of Shanghai Municipality [20230742300, 18595800700]

    Keywords: Aramid nanofibers; Carboxylated cellulose nanofibrils; Vacuum heat treatment; Dielectric properties; Metal-organic frameworks

    The design of flexible polymeric films with internal porous structures has received increasing attention in low dielectric applications. The highly porous metal-organic frameworks (MOFs) of [Cu 3 (BTC) 2 ] n (BTC = benzene-1,3,5-tricarboxylate) were introduced into aramid nanofibers (ANF) matrix by using carboxylated cellulose nanofibrils (CNF) as carriers to obtain strong, flexible, and ultra-low dielectric films. The well-dispersed flowers-branch like CNF@CuBTC through in-situ growth of CuBTC on CNF surface endowed the ANF/CNF@CuBTC films with excellent thermal stability, mechanical integrity and low dielectric properties. Besides, the flexible dielectric films exhibited superior ultraviolet (UV) resistance, lower coefficient of thermal expansion (4.28 x10 -5 degrees C - 1 ) and increased water contact angle (83.81 degrees). More interestingly, the removal of guest molecules from the ANF/CNF@CuBTC films according to the vacuum heat treatment (VHT) process significantly improved their dielectric response. The specific surface areas of the composite films after VHT increased obviously, and the dielectric constant and dielectric loss tangent decreased to the expected 1.8-2.2 and 0.0 01-0.03 at 10 0 MHz, respectively. Consequently, such designable ultra-low dielectric films with high flexibility play an incredible significance in applications of microelectronics under large deformation conditions, especially in flexible/wearable devices at the arrival of 5 G era.
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