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In Situ Investigation on the Effect of Salinity and pH on the Asphaltene Desorption under Flowing Conditions

Year: 2021

Journal: Energy Fuels, Volume 35, NOV 18, page 18478–18483

Authors: Yang, Hui; Wang, Shujuan; Wu, Jiazhong; Yang, Siyu; Zhang, Wei; Yang, Ming; Fan, Minghong; Wang, Jinben

Organizations: National Natural Science Foundation of China [21872152]; PetroChina Innovation Foundation [2020D-5007-0501]; Important National Science and Technology Specific Project of China [2017ZX05013-003]; Strategic Priority Research Program of CAS [XDB22030102]

There is a limited understanding of the microscale interactions between fluid-oil-solid interfaces, which could be a stumbling block to the development of relevant technologies and industries. With this in mind, we applied an in situ method, quartz crystal microbalance with dissipation (QCM-D), on the interactions among the fluid-oil-solid phases and investigated the desorption process of the asphaltene model molecule from silica surfaces during a flow of LSW at the conditions of different ion types, salinities, or pH values. The salinity effect plays a bigger role than that of the pH effect on the asphaltene desorption and, furthermore, the divalent ions (such as SO42-, Mg2+, or Ca2+) show a stronger effect than that of monovalent ions (such as Cl-, Na+, or K+). Our study provides a new strategy for the investigation of the interactions between fluid-oil-solid interfaces.