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    Irregular dot array nanocomposite molecularly imprinted membranes with enhanced antibacterial property: Synergistic promotion of selectivity, rebinding capacity and flux

    Year: 2021

    Journal: Chem. Eng. J., Volume 405, FEB 1

    Authors: Lu, Jian; Qin, Yingying; Li, Chunxiang; Wu, Yilin; Meng, Minjia; Dong, Zeqing; Sun, Chang; Chen, Muning; Yan, Yongsheng

    Organizations: National Natural Science Foundation of China [21808089, 21878120, 51803080, 21777062]; Natural Science Foundation of Jiangsu Province [BK20191228, BK20180886, BK20180192, BK20171314, BK20171316]; China Postdoctoral Science Foundation [2019M661750]

    Keywords: Irregular dot array structure; Molecularly imprinted membrane; Synergistic Promotion; Selective separation; Bisphenol A

    Molecularly imprinted membranes capable of selective separation simultaneously desire superior selectivity, rebinding capacity and flux, where multi-microporous substrates and closely arranged molecularly imprinted polymers are demanded. The combination of hierarchical-microporous membranes and molecularly imprinted polymers with irregular dot array distribution provides a potential superiority. In present work, irregular dot array nanocomposite bisphenol A (BPA)-molecularly imprinted membranes (BPA-MIMs) with synergistically promotional performance were developed by a modification-by-imprinting strategy: (i) Hydrophilic and antibacterial modifications were implemented on hierarchical-microporous substrate membranes to improve the specific functionalities. (ii) BPA-imprinted polymers with irregular dot array structures were synthesized by mercapto-alkenes click chemistry. Based on specific design and optimization, selectivity, rebinding capacity and flux were synergistically enhanced onto the as-developed BPA-MIMs. The impressive permselectivity coefficients (beta(BIP/BPA) = 2.78, beta(HQ/BPA) = 7.57) with acceptable fluctuation (7.85% for beta(BIP/BPA) and 9.49% for beta(HQ/BPA)) demonstrate the superior selectivity and stability of BPA-MIMs. Importantly, the concentration-dependent and time-dependent cumulative selectivity verifies the leading contribution of the irregular dot array nanocomposite structure. Remarkable performance in semi-practical operations suggests the effectiveness of BPA-MIMs even in complex environment. The BPA-MIMs, as well as the methodology, developed in this work will provide significant potentials for membrane-based water treatment and even specific separation.
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