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    Transparent films by ionic liquid welding of cellulose nanofibers and polylactide: Enhanced biodegradability in marine environments

    Year: 2021

    Journal: J. Hazard. Mater., Volume 402, JAN 15

    Authors: Niu, Xun; Huan, Siqi; Li, Haiming; Pan, Hui; Rojas, Orlando J.

    Organizations: National Natural Science Foundation of China [31770631]; Canada Excellence Research Chair initiative, Government of Canada the Canada Foundation for Innovation; European Research Council under the European Union [788489]

    Keywords: Polylactide; Cellulose Nanofibers; Ionic liquid welding; Degradation; Seawat e r

    We introduce a green and facile method to compatibilize hydrophobic polylactide (PLA) with hydrophilic cellulose nanofibers (CNF) by using ionic liquid ([DBNH][OAc]) welding with a cosolvent system (gamma-valerolactone). Such welding affords strong (230 MPa tensile strength), flexible (13% elongation at break), transparent (>90%) and defect-free CNF/PLA films. The films are biodegradable in marine environments (70% degradation in 7 weeks), facilitating the otherwise slow PLA decomposition. Physical, chemical and structural features of the films before and after welding are compared and factored in the trends observed for degradation in seawater. The results point to the possibility of PLA-based films forming a co-continuous system with nanocellulose to achieve an improved performance. The role of film morphology, hydrophobicit y , and crystallinit y is discussed to add to the prospects for packaging materials that simultaneously display accelerated degradability in marine environments.