Soft Matter and Wetting research group at Aalto University published insights about superhydrophobic surfaces in Science recently [1]. The non-wetting surfaces have experienced an enormous boost of interest after the observation of superhydrophobicity and self-cleaning effect in natural lotus leaves
Research interest has grown exponentially since the late 1990s due to its tremendous application potential in areas such as self-cleaning, anti-icing, drag reduction and enhanced heat transfer.
By a common definition, a surface is considered superhydrophobic if the water contact angle is larger than 150° and if the water droplets readily slide off the surface.
How to characterize wettability on superhydropic surfaces?
Authors call for standardized testing for these novel surfaces as the lack of standardization usually makes comparison of different reported results impossible. They pointed out that variety of methods have been used to test the durability of superhydrophobic surfaces, including linear abrasion, circular abrasion, tape peeling, blade scratching, sand abrasion, ball-on-disk sliding, oscillating steel ball, and water jet tests. An additional issue is that surface wetting is often not characterized in the most useful manner. Wetting characterization was recommended to include both droplet mobility and the advancing and receding contact angles (Dynamic contact angle analysis). Authors did not recommend to use the static contact angle as it is not easily affected by abrasion. It is imperative to characterize the effect of wear in terms of change in contact angle hysteresis i.e. difference between advancing and receiving angles, or just in the receding contact angle. Alternatively, the sliding or roll-off angle was recommended, as it is related to contact angle hysteresis.
To learn more how to study superhydrophobic surfaces, see the webinar by Prof. Robin Ras.
1. Tian X., Verho T., Ras R.H.A., Moving superhydrophobic surfaces toward real-world applications, Science 352, 142-143 (2016).
Photo: Water droplets rolling on a superhydrophobic surface. The repellency of a superhydrophobic surface immersed in water causes a depression in the water, and the surface under water has a silvery shine caused by a microscopic layer of air trapped between the water and the superhydrophobic surface. Photo by Mika Latikka, Aalto University.
One of the major factors limiting the analysis of contact angles is the accurate assignment of the baseline.
The earliest known reference to contact angle measurement was made by Thomas Young in 1805.
Chemical etching of fluoropolymers is a process used to selectively remove material from the surface using chemical solutions to improve wettability.
This difference in wettability is key in determining how each membrane is used.
Drop volume can have an effect on contact angles on certain surfaces.
Advancing contact angle is the highest possible contact angle measured on a previously unwetted solid surface.
Roughness corrected contact angle, is an angle where the effect of surface roughness is taken away.
Instead, one can measure static contact angles, advancing and receding contact angles, and roughness corrected contact angles.
For the mechanical performance of the composite, the adhesion between fiber and the matrix is of utmost importance.